Effect of rapidly changing river stage on uranium flux through the hyporheic zone   总被引：2，自引：1，他引：1  

Fritz BG  Arntzen EV 《Ground water》2007,45(6):753-760

Measurement of ground water/surface water interaction within the hyporheic zone is increasingly recognized as an important aspect of subsurface contaminant fate and transport. Understanding the interaction between ground water and surface water is critical in developing a complete conceptual model of contaminant transport through the hyporheic zone. At the Hanford Site near Richland, Washington, ground water contaminated with uranium discharges to the Columbia River through the hyporheic zone. Ground water flux varies according to changes in hydraulic gradient caused by fluctuating river stage, which changes in response to operation of dams on the Columbia River. Piezometers and continuous water quality monitoring probes were installed in the hyporheic zone to provide long-term, high-frequency measurement of hydraulic gradient and estimated uranium concentrations. Subsequently, the flux of water and uranium was calculated for each half-hour time period over a 15-month study period. In addition, measurement of water levels in the near-shore unconfined aquifer enhanced the understanding of the relationship between river stage, aquifer elevation, and uranium flux. Changing river stage resulted in fluctuating hydraulic gradient within the hyporheic zone. Further, influx of river water caused lower uranium concentrations as a result of dilution. The methods employed in this study provide a better understanding of the interaction between surface and ground water in a situation with a dynamically varying vertical hydraulic gradient and illustrate how the combination of relatively standard methods can be used to derive an accurate estimation of water and contaminant flux through the hyporheic zone.  相似文献   

Fault controlled Carboniferous A-type magmatism in the proto-Andean foreland (Sierras Pampeanas,Argentina): Geochemical constraints and petrogenesis     

Juan A. Dahlquist  Pablo H. Alasino  G. Nelson Eby  Carmen Galindo  César Casquet 《Lithos》2010,115(1-4):65-81

The intrusion of granitoids into the Eastern Sierras Pampeanas in the Early Carboniferous took place after a long period of mainly compressional deformation that included the Famatinian (Ordovician) and Achalian (Devonian) orogenies. These granitoids occur as small scattered plutons emplaced in a dominant extensional setting, within older metamorphic and igneous rocks, and many of them are arranged along a reactivated large shear zone. A set of 46 samples from different granitic rocks: Huaco granitic complex, San Blas pluton, and the La Chinchilla stock from the Sierra de Velasco, Zapata granitic complex from Sierra de Zapata, and the Los Árboles pluton from Sierra de Fiambalá, display high and restricted SiO₂ contents between 69.2 and 76.4 wt.%. On both FeO/(FeO + MgO) vs. SiO₂ and [(Na₂O + K₂O) ? CaO] vs. SiO₂ plots the samples plot in the ferroan and alkaline-calcic to calco-alkaline fields (FeO/(FeO + MgO) = 0.88–1.0%;[(Na₂O + K₂O) ? CaO] = 6.3–8.3%), thus showing an A-type granitoid signature. The high concentrations for the High Field Strength Elements (HSFE), such as Y, Nb, Ga, Ta, U, Th, etc. and flat REE patterns showing significant negative Eu anomalies are also typical features of A-type granites. Our petrogenetic model supports progressive fractional crystallization with dominant fractionation of feldspar and a source mineral assemblage enriched in plagioclase. Biotites have distinctive compositions with high FeO/MgO ratios (7.8–61.5), F (360–5610 ppm), and Cl (120–1050 ppm). The FeO/MgO ratios together with the F and Cl content of igneous biotites seem to reflect the nature of their parental host magmas and may be useful in identifying A-type granitoids. The isotopic data (Rb–Sr and Sm–Nd) confirm that the A-type granites represent variable mixtures of asthenospheric mantle and continental crust and different mixtures lead to different subtypes of A-type granite (illustrating the lack of consensus about A-type magma origin). We conclude that prominent shear zones play an important role in providing suitable conduits for ascending asthenospheric material and heat influx in the crust, a hypothesis that is in accord with other recent work on A-type granites.  相似文献   

Climatic and environmental controls on the occurrence and distributions of long chain alkenones in lakes of the interior United States   总被引：1，自引：0，他引：1  

Jaime L. Toney  Yongsong Huang  Sherilyn C. Fritz  Eric Grimm 《Geochimica et cosmochimica acta》2010,74(5):1563-7565

Long chain alkenones (LCA) are temperature-sensitive lipids with great potential for quantitative reconstruction of past continental climate. We conducted the first survey for alkenone biomarkers from 55 different lakes in the Northern Great Plains and Nebraska Sand Hills of the United States. Among those surveyed, we found 13 lakes that contain LCAs in the surface sediments. The highest concentrations of alkenones in sediments are found in cold (mean annual air temperature ∼11 °C versus 17 °C in our warmest sites), brackish to mesosaline (salinity = 8.5-9.7 g/L), and alkaline (pH = 8.4-9.0) lakes with high concentrations of sodium and sulfate. The dynamics of stratification and nutrient availability also appear to play a role in LCA abundance, as early spring mixing promotes a bloom of alkenone-producing haptophytes. Four of the alkenone-containing sites contain the C_37:4 alkenone; however, we discovered an unprecedented lacustrine alkenone distribution in a cluster of lakes, with a total absence of C_37:4 alkenone. We attribute this unusual composition to a different haptophyte species and show that the sulfate:carbonate ratio may control the occurrence of these two distinct populations. We created a new in-situ temperature calibration for lacustrine sites that contain C_37:4 using a water-column calibration from Lake George, ND and show that is linearly correlated to lake water temperature (R² = 0.74), but is not. A number of lakes contain an unidentified compound series that elutes close to the LCAs, highlighting the importance of routine GC-MS examination prior to using lacustrine LCAs for paleotemperature reconstructions.  相似文献   

Alfred E. Bergeat (1866–1924): a distinguished volcanologist and ore deposit researching scientist at the mining academies of Freiberg (Saxony) and Clausthal (Harz mountains) in Germany     

Fritz A. Pfaffl 《International Journal of Earth Sciences》2010,99(4):949-954

Alfred E. Bergeat, originated from a family, who produced gold-glance in a factory (porcelain painting), studied mineralogy and geology at the University of Munich from 1886 to 1892. Due to the results of his habilitation work on the volcanism of island arcs, especially of the Stromboli volcanic island in the Tyrrhenian Sea, he became a recognized volcanologist and specialist in volcanic petrography. He further became an explorer of syngenetic, epigenetic and deuterogenic ore deposits at the mining academies (Bergakademien) of Freiberg (Saxony) and Clausthal (Harz mountains). He described these ore deposits in a two-volume manual (1904–1906) which was summarized again in 1913. After his early death in 1924, the two manuals “Die Vulkane” (1925) and “Vulkankunde” (1927) were posthumously published by his colleague and friend Karl Sapper (1866–1945).  相似文献   

Strontium as a tracer of weathering processes in a silicate catchment polluted by acid atmospheric inputs, Strengbach, France   总被引：4，自引：0，他引：4  

A. Probst  A. El Gh''mari  D. Aubert  B. Fritz  R. McNutt   《Chemical Geology》2000,170(1-4):203-219

This paper determines the weathering and atmospheric contributions of Ca in surface water from a small spruce forested silicate catchment (N–E France) receiving acid atmospheric inputs. The bedrock is a granite with K-feldspar and albite as dominant phases. The calcium content in plagioclase is low and the Ca/Na ratio in surface water is high, reflecting other sources of calcium from those expected from the weathering of major mineral phases. The biotite content is low. Only traces of apatite were detected while no calcite was found in spite of a major hydrothermal event having affected the granite. The strontium isotopic ratio ⁸⁷Sr/⁸⁶Sr and Sr content was used as a tracer of weathering and was determined in minerals and bulk bedrock, open field precipitation, throughfall, soil solution, spring and stream water. The Sr isotopic ratio of the reacting weathering end-member was predicted by simulating the alteration of the granite minerals by incorporating strontium into the water–rock interaction kinetic code KINDIS. In the early stages of water–rock interaction, K-feldspar and biotite strongly influence the isotopic composition of the weathering solution whereas, the Na-rich plagioclase appears to be the main long-term reactive weathering end-member. Approximately 50% of dissolved Sr in streamwater are atmospherically derived. The ⁸⁷Sr/⁸⁶Sr ratios of exchangeable Sr in the fine fraction at 1-m depth from a soil profile indicate that the amount of exchangeable Sr seems essentially controlled by atmospheric inputs. The exception is the deep saprolite where weathering processes could supply the Sr (and Ca). Na-Plagioclase weathering obviously control the chemistry and the isotopic composition of surface waters. The weathering of trace mineral plays a secondary role, the exception is for apatite when plagioclase is absent. Our hydrochemical, mineralogical and isotopic investigations show that a major part of the strong Ca losses detected in catchment hydrochemical budgets that result from the neutralization of acid precipitation has an atmospheric origin. Consequently, in the long term, in such areas, the availability of such an exchangeable base cation might be strongly limited and surface waters consequently acidified.  相似文献   

Preliminary investigation results on fabrics and related physical properties of an anisotropic gneiss     

F. J. Brosch  K. Schachner  M. Blümel  A. Fasching  H. Fritz 《Journal of Structural Geology》2000,22(11-12)

In order to evaluate the fabric-dependent anisotropy of a particular gneiss type, we assessed the quartz lattice and shape preferred orientations as well as the microcrack pattern statistics. In the rock mechanics laboratory, several strength and deformability tests on drilled rock samples were run and the seismic wave propagation properties along the rock’s principal strain axes were determined. In the mechanical tests it turned out that despite a distinct stretching lineation with initially extreme grain elongation, the rock performs for the larger part as a transversely isotropic material with the schistosity as plane of isotropy. The anisotropy in seismic wave propagation within the plane of schistosity is attributed primarily to a highly anisotropic microcrack pattern, the distinct gneissose banding and to a lower degree to the LPO of quartz.  相似文献   

MACS for Global measurement of the Solar wind velocity and the Thermal electron temperature during the Total solar eclipse on 11 August 1999     

Reginald  Nelson L.  Davila  Joseph M. 《Solar physics》2000,195(1):111-122

MACS for Multi-Aperture Coronal Spectrometer is a fiber-optic-based spectrograph designed and used to perform global measurement of the solar wind velocity and the thermal electron temperature of the solar corona during the total solar eclipse on 11 August 1999. The motivation for the construction of MACS was provided by the theory formulated by Cram (1976) for the formation of the K-coronal spectrum and a method for determining the radial profile of the thermal electron temperature of the solar corona. Based on this theory a subsequent application was carried out by Ichimoto et al. (1996) using a slit-based spectroscopic study during the total solar eclipse on 3 November 1994. We have modified Cram's theory to incorporate the role of the solar wind velocity in the formation of the K-corona and have identified wind and temperature sensitive intensity ratios. Instead of a slit-based spectrograph MACS consists of twenty fiber optic tips placed at the focal plane of the telescope and positioned to see different radii and latitudes of the solar corona. Another fiber is placed at the center of the frame and uses the lunar shadow for a measure of the background signal. The other ends of the fibers are vertically aligned and placed at the primary focus of the collimating lens of the spectrograph thus providing simultaneous spectra from all of the fibers. In this first paper (Paper I) we describe our instrument and the obtained coronal spectra. The final and complete results will be presented in Paper II (Reginald and Davila, 2000).  相似文献   

Modelling localized sources of sediment in mountain catchments for provenance studies     

Giulia Battista  Fritz Schlunegger  Paolo Burlando  Peter Molnar 《地球表面变化过程与地形》2020,45(14):3475-3487

A hydrology–sediment modelling framework based on the model Topkapi-ETH combined with basin geomorphic mapping is used to investigate the role of localized sediment sources in a mountain river basin (Kleine Emme, Switzerland). The periodic sediment mobilization from incised areas and landslides by hillslope runoff and river discharge is simulated in addition to overland flow erosion to quantify their contributions to suspended sediment fluxes. The framework simulates the suspended sediment load provenance at the outlet and its temporal dynamics, by routing fine sediment along topographically driven pathways from the distinct sediment sources to the outlet. We show that accounting for localized sediment sources substantially improves the modelling of observed sediment concentrations and loads at the outlet compared to overland flow erosion alone. We demonstrate that the modelled river basin can shift between channel-process and hillslope-process dominant behaviour depending on the model parameter describing gully competence on landslide surfaces. The simulations in which channel processes dominate were found to be more consistent with observations, and with two independent validations in the Kleine Emme, by topographic analysis of surface roughness and by sediment tracing with ¹⁰ Be concentrations. This research shows that spatially explicit modelling can be used to infer the dominant sediment production process in a river basin, to inform and optimize sediment sampling strategies for denudation rate estimates, and in general to support sediment provenance studies. © 2020 John Wiley & Sons, Ltd.  相似文献   

Landslides control the spatial and temporal variation of channel width in southern Taiwan: Implications for landscape evolution and cascading hazards in steep,tectonically active landscapes          下载免费PDF全文

Brian J. Yanites  Nate A. Mitchell  Joshua C. Bregy  Grace A. Carlson  Kirstyn Cataldo  Margaret Holahan  Graham H. Johnston  Amelia Nelson  Jeffery Valenza  Matthew Wanker 《地球表面变化过程与地形》2018,43(9):1782-1797

Intense precipitation or seismic events can generate clustered mass movement processes across a landscape. These rare events have significant impacts on the landscape, however, the rarity of such events leads to uncertainty in how they impact the entire geomorphic system over a range of timescales. Taiwan is steep, tectonically active, and prone to landslide and debris flows, especially when exposed to heavy rainfall events. Typhoon Morakot made landfall in Taiwan in August of 2009, causing widespread landslides in southern Taiwan. The south to north trend in valley relief in southern Taiwan leads to spatial variability in landslide susceptibility providing an opportunity to infer the long‐term impact of such landslide events on channel morphology. We use pre‐ and post‐typhoon imagery to quantify the propagating impact of this event on channel width as the debris is routed through the landscape. The results show the importance of cascading hazards from landslides on landscape evolution based on patterns of channel width (both pre‐ and post‐typhoon) and hillslope gradients in 20 basins along strike in southern Taiwan. Prior to Typhoon Morakot, the river channels in the central part of the study area were about 3–10 times wider than the channels in the south. Following the typhoon, aggradation and widening was also a maximum in these central to northern basins where hillslope gradients and channel steepness is high, accentuating the pre‐typhoon pattern. The results further show that the narrowest channels are located where channel steepness is the lowest, an observation inconsistent with a detachment‐limited model for river evolution. We infer this pattern is indicative of a strong role of sediment supply, and associated landslide events, on long‐term channel evolution. These findings have implications across a range of spatial and temporal scales including understanding the cascade of hazards in steep landscapes and geomorphic interpretation of channel morphology. Copyright © 2018 John Wiley & Sons, Ltd.  相似文献   

Zielvorgaben für Pflanzenschutzmittelwirkstoffe und andere Schadstoffe in Oberflächengewässern     

Jutta Jahnel  Christian Zwiener  Thomas J. Gremm  Gudrun Abbt‐Braun  Fritz H. Frimmel  Carola Kussatz  Dieter Schudoma  Werner Rocker 《洁净——土壤、空气、水》2001,29(4):246-253

Quality Targets for Pesticides and Other Pollutants in Surface Waters Surface waters are not only adversely affected by industrial and municipal wastewaters but also by diffuse sources. For the control of the ecological water quality, so‐called quality targets are set. The quality targets are threshold concentrations for hazardous substances related to the protected goods like water ecosystems, drinking water supply, sediments, or fishing. In this paper, quality targets for the protection of aquatic life in surface waters were derived on the basis of a concept developed by the International Commission for the Protection of the Rhine (Internationale Kommission zum Schutze des Rheins – IKSR). The quality targets for the selected hazardous substances, which mainly belong to the chemical class of pesticides, were calculated using ecotoxicological results for species of bacteria, algae, fish, and small crustaceans, as the four trophic standards of the water ecosystem. In cooperation with the Federal Environmental Agency (Umweltbundesamt – UBA) the effect data were taken from ecotoxicological data bases. According to the concept of the IKSR, the lowest test result for the most sensitive species was multiplied by an assessment factor. This proceeding concerns the difficulty in describing the complex interactions in water ecosystems with toxicity data of single laboratory experiments for a few organisms. For seven pesticides quality targets below 0.1 μg/L were proposed. These results show that the ecotoxicologically based quality targets might be even lower than the limit values for pesticides in drinking water of 0.1 μg/L. But for most of the substances the determined values are significantly higher. The great concentration range of quality targets demonstrates distinctly that one standard concentration for all pesticides could not be given with regard to the different effects on aquatic organisms.  相似文献